Free Radical Addition of Thiophenol to 3-Substituted 1-Alkyne with or without Migration of the Substituents
نویسندگان
چکیده
منابع مشابه
Computational study of the rate constants and free energies of intramolecular radical addition to substituted anilines
The intramolecular radical addition to aniline derivatives was investigated by DFT calculations. The computational methods were benchmarked by comparing the calculated values of the rate constant for the 5-exo cyclization of the hexenyl radical with the experimental values. The dispersion-corrected PW6B95-D3 functional provided very good results with deviations for the free activation barrier c...
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ژورنال
عنوان ژورنال: Bulletin of the Chemical Society of Japan
سال: 1988
ISSN: 0009-2673,1348-0634
DOI: 10.1246/bcsj.61.3752